Search results for "Coulometric titration"

showing 2 items of 2 documents

Complex Formation of the Uranyl (UO22+) Ion with the Diethylene Triaminopentaacetate (DTPA) Ligand at 25 °C in 3 M Sodium Perchlorate

2011

The complex formation between the uranyl (UO22+) ion and the diethylene triaminopentaacetate ligand (DTPA) has been investigated at 25 °C, in a 3 M sodium perchlorate medium. The overall protonation constants βjH of the free ligand have been previously determined in this ionic medium: six protonated species (HjA), with j ranging from 1 to 6, together with the free anion A5− have been identified in the concentration range from (3·10−3 to 13·10−3) mol·kg−1. Four complex species, H2UO2A−, HUO2A2−, UO2A3−, and UO2AOH4−, have been identified in the total uranyl concentration range from (1.1·10−3 to 5.7·10−3) mol·kg−1, and their overall stability constants determined, keeping the metal to ligand …

LigandGeneral Chemical EngineeringInorganic chemistrycomplexes formation • solution equilibria • coulometric titration • emf measurements • organic ligand stability constants.Ionic bondingProtonationGeneral ChemistrySodium perchlorateUranylIonMetalchemistry.chemical_compoundchemistryvisual_artvisual_art.visual_art_mediumSettore CHIM/01 - Chimica AnaliticaChelationJournal of Chemical & Engineering Data
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Could the acid-base status of Antarctic sea urchins indicate a better-than-expected resilience to near-future ocean acidification?

2015

Increasing atmospheric carbon dioxide concentration alters the chemistry of the oceans towards more acidic conditions. Polar oceans are particularly affected due to their low temperature, low carbonate content and mixing patterns, for instance upwellings. Calcifying organisms are expected to be highly impacted by the decrease in the oceans' pH and carbonate ions concentration. In particular, sea urchins, members of the phylum Echinodermata, are hypothesized to be at risk due to their high-magnesium calcite skeleton. However, tolerance to ocean acidification in metazoans is first linked to acid-base regulation capacities of the extracellular fluids. No information on this is available to dat…

Ocean Acidification International Coordination Centre (OA-ICC)SalinityNotocidaris gaussensisBicarbonate ion standard deviationinorganicAlkalinity total standard deviationAlkalinityCoulometric titrationExperimentCarbon inorganic dissolvedTemperature waterSizeCoelomic fluidCalculated using seacarb after Nisumaa et al 2010CalculatedAragonite saturation stateCtenocidaris giganteaAlkalinity totaltotalAmphipneustes loriolipHTemperaturedissolvedAcid base regulationCarbonate ionPartial pressure of carbon dioxide (water) at sea surface temperature (wet air)Carbon dioxide standard deviationSterechinus neumayeriEarth System ResearchAporocidaris eltanianaδ13Cstandard deviationField observationPolarStation labelEchinodermataPotentiometric titrationCalcite saturation stateCoelomic fluid alkalinityPotentiometricwaterPartial pressure of carbon dioxideAmphipneustes similisAragonite saturation state standard deviationBenthosDATE TIMEOcean Acidification International Coordination Centre OA ICCSterechinus antarcticusAnimaliaCalcite saturation state standard deviationBicarbonate ionLONGITUDECalculated using seacarb after Nisumaa et al. (2010)SpeciesCalculated using CO2SYScarbonEvent labelPartial pressure of carbon dioxide standard deviationCoelomic fluid carbon inorganic dissolvedCarbonate system computation flagAcid-base regulationpH standard deviationCarbonate ion standard deviationFugacity of carbon dioxide (water) at sea surface temperature (wet air)Amphipneustes rostratusPartial pressure of carbon dioxide water at sea surface temperature wet airDATE/TIMECarbon dioxideDifferenceSingle speciesCoelomic fluid pHLATITUDEFugacity of carbon dioxide water at sea surface temperature wet airAntarcticBenthic animalsCoast and continental shelfAbatus cavernosus
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